NT CAT PC-8 CAS No.:98-94-2 Synthesis method and application Brief introduction. Chemical Chinese name: N,N-dimethylcyclohexylamine Chemical English name: N,N-dimethylcyclohexylamine; dimethyl aminocy clohexane Chemical Alias: Dimethyl aminocyclohexane CAS No.: 98-94-2 EC No.: 202-715-5 Molecular formula: C8H17N Synthesis method. N,N-dimethylaniline catalytic chlorination method In 1904, Sabatier et al. carried out the gas-phase hydrogenation of N,N a dimethylamine at a temperature of 160-180°C and at atmospheric pressure to produce DMCHA. Phenol method This method uses Pd or Rh as the catalyst, and phenol dimethylamine and hydrogen as raw materials. For example, when Pd is the catalyst, the catalyst dosage is 0.2~0.5, and the process conditions are 60~150℃, hydrogen pressure 0.15~0.48MPa, reaction time 6h, and the yield is between 70~80%. The raw material is available, and the reaction conditions are mild, but the catalyst is made of precious metals, and the yield is low. Cyclohexylamine method The process also uses formaldehyde and formic acid to react with cyclohexylamine, or uses oxides of Bi, Sb, Mg, A1, Lu, etc. as catalysts to react cyclohexylamine with methanol to methylate cyclohexylamine to produce DMCHA. the disadvantage of this method is the low selectivity of the former reaction, and the yield of the later methylation is not high. Cyclohexanone method Among the methods for the synthesis of DMCHA, the reductive amination method using cyclohexanone as raw material has more advantages: high conversion, yield and selectivity. The processes using Pd/C catalyst or Cu-A1 catalyst have their own characteristics and are currently under development in China. Uses. [Use I] Mainly used as polyurethane hard foam catalyst [Use II] N,N-dimethylcyclohexylamine can be used in a wide range of rigid foams. N,N-Dimethylcyclohexylamine is also suitable for the manufacture of rigid foam furniture frames and decorative parts. It can be used as the main catalyst alone in rigid foam products without the addition of organotin, or it can be supplemented with JD series catalysts according to the process and product requirements. It is also used as intermediate of rubber accelerator and synthetic fiber. Use III】It is used as intermediate of dyestuff, used to make vanillin, azo dyestuff, triphenylmethane dyestuff, also can be used as solvent, stabilizer, analysis reagent, etc.. Also used as catalyst. Storage and transportation. Should be sealed and stored in a dry, cool and ventilated warehouse Package: 200KG/drum 200KG/drum Storage: It is recommended to store in dry and cool area with proper ventilation. Please fasten the lid as soon as possible after original packaging to prevent the mixing of other substances such as moisture and other substances from affecting the product performance. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits. More:https://www.newtopchem.com/archives/40458

NT CAT PC-8 CAS No.:98-94-2 Synthesis method and application Brief introduction. Chemical Chinese name: N,N-dimethylcyclohexylamine Chemical English name: N,N-dimethylcyclohexylamine; dimethyl aminocy clohexane Chemical Alias: Dimethyl aminocyclohexane CAS No.: 98-94-2 EC No.: 202-715-5 Molecular formula: C8H17N Synthesis method. N,N-dimethylaniline catalytic chlorination method In 1904, Sabatier et al. carried out the gas-phase hydrogenation of N,N a dimethylamine at a temperature of 160-180°C and at atmospheric pressure to produce DMCHA. Phenol method This method uses Pd or Rh as the catalyst, and phenol dimethylamine and hydrogen as raw materials. For example, when Pd is the catalyst, the catalyst dosage is 0.2~0.5, and the process conditions are 60~150℃, hydrogen pressure 0.15~0.48MPa, reaction time 6h, and the yield is between 70~80%. The raw material is available, and the reaction conditions are mild, but the catalyst is made of precious metals, and the yield is low. Cyclohexylamine method The process also uses formaldehyde and formic acid to react with cyclohexylamine, or uses oxides of Bi, Sb, Mg, A1, Lu, etc. as catalysts to react cyclohexylamine with methanol to methylate cyclohexylamine to produce DMCHA. the disadvantage of this method is the low selectivity of the former reaction, and the yield of the later methylation is not high. Cyclohexanone method Among the methods for the synthesis of DMCHA, the reductive amination method using cyclohexanone as raw material has more advantages: high conversion, yield and selectivity. The processes using Pd/C catalyst or Cu-A1 catalyst have their own characteristics and are currently under development in China. Uses. [Use I] Mainly used as polyurethane hard foam catalyst [Use II] N,N-dimethylcyclohexylamine can be used in a wide range of rigid foams. N,N-Dimethylcyclohexylamine is also suitable for the manufacture of rigid foam furniture frames and decorative parts. It can be used as the main catalyst alone in rigid foam products without the addition of organotin, or it can be supplemented with JD series catalysts according to the process and product requirements. It is also used as intermediate of rubber accelerator and synthetic fiber. Use III】It is used as intermediate of dyestuff, used to make vanillin, azo dyestuff, triphenylmethane dyestuff, also can be used as solvent, stabilizer, analysis reagent, etc.. Also used as catalyst. Storage and transportation. Should be sealed and stored in a dry, cool and ventilated warehouse Package: 200KG/drum 200KG/drum Storage: It is recommended to store in dry and cool area with proper ventilation. Please fasten the lid as soon as possible after original packaging to prevent the mixing of other substances such as moisture and other substances from affecting the product performance. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits. More:https://www.newtopchem.com/archives/40458

DMAEE CAS:1704-62-7 Usage and Manufacturing Method Brief introduction. Dimethyldiethanolamine is a chemical substance. Alias: Dimethylaminoethoxyethanol Abbreviation: DMAEE English name: dimethyaminoethoxyethanol, dimethyl2-(2-aminoethoxy)ethanol Molecular formula: C6H15NO2 Relative molecular weight:133.2 CAS No.:1704-62-7 Formulation. Recipe weight:133.19 Purity percentage: ≥98.0% (GC) Physical form: Liquid Experimental operation. [ 50-00-0 ] + [ 929-06-6 ] = [ 1704-62-7 ] Phase I: 0.5 hr. Phase II: 100 - 110 °C; 2 h. Phase III: 120 °C; 4 h. Synthesis To a 250 ml three-necked flask was added 63.1 g of diethyleneglycolamine (0.6 mol), 34.5 g of paraformaldehyde (1.2 mol), stirred for 30 min and 63 g of formic acid (1.2 mol, 88%) was added dropwise at a temperature of 100 to 110 °C and reacted at about 100 °C for 1 h. Distill out 30 g under reduced pressure (vacuum - 0.094 MPa, kettle temperature 80°C). The distillation ended with 90.0% product and 9.8% impurity (S-2) content. _: The liquid from step 2) was transferred to a 500 ml distillation flask and distilled under reduced pressure at a vacuum of -0.094 mpa. 62°C component was n-butanol ester exchanged down to formic acid as butanol, 121° C DMAEE component that is the product. Collected 121 ° C component 128.3g, yield 96.5%, the Uses. DMAEE is a low odor reactive foaming catalyst, mainly used in rigid packaging foam, also used in molded flexible foam and polyether urethane flexible foam.DMAEE is also an important intermediate, used in polyurethane coatings, surfactants, mine reinforcement and many other fields. Zhongke's organic amine catalyst and curing agent series products will be put into production one after another, and the core catalyst and curing agent products will be used as the basis for the subsequent development of new materials for high value-added polyurethane and epoxy resin by precisely matching the market changes. Integrated manufacturing method of dmae and dmaee in microtubular reactor. A method of integrated preparation of DMAE and DMAEE in microtube reactor is disclosed, which includes the following steps in turn: pumping ethylene oxide and aqueous dimethylamine solution formed by mixing dimethylamine with water as catalyst as materials into the microtube reactor respectively, controlling the molar ratio of ethylene oxide to dimethylamine as 1~2:1; setting the reaction temperature in the microtube reactor as 60~90°C and pressure as 1.3 ±0.2 Pa, and the residence time of the material in the microtubular reactor is controlled to be 15～90s; the effluent from the microtubular reactor is an aqueous solution of DMAE and DMAEE. The method of the present invention has the advantages of high atomic economy, good reaction selectivity, mild reaction conditions, short reaction time, simple catalyst, and simple product separation. Safety information : Risk terminology R21:Harmful in contact with skin. R41:Risk of serious damage to the eyes. Safety Terminology S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. Storage and transportation. Should be kept sealed and stored in a dry, cool, ventilated warehouse Packaging. 200KG/drum Storage: It is recommended to store in a dry and cool area with proper ventilation. After the original packaging, please fasten the lid as soon as possible to prevent the mixing of other substances such as moisture to affect the performance of the product. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits. More:https://www.newtopchem.com/archives/40565

DMAEE CAS:1704-62-7 Usage and Manufacturing Method Brief introduction. Dimethyldiethanolamine is a chemical substance. Alias: Dimethylaminoethoxyethanol Abbreviation: DMAEE English name: dimethyaminoethoxyethanol, dimethyl2-(2-aminoethoxy)ethanol Molecular formula: C6H15NO2 Relative molecular weight:133.2 CAS No.:1704-62-7 Formulation. Recipe weight:133.19 Purity percentage: ≥98.0% (GC) Physical form: Liquid Experimental operation. [ 50-00-0 ] + [ 929-06-6 ] = [ 1704-62-7 ] Phase I: 0.5 hr. Phase II: 100 - 110 °C; 2 h. Phase III: 120 °C; 4 h. Synthesis To a 250 ml three-necked flask was added 63.1 g of diethyleneglycolamine (0.6 mol), 34.5 g of paraformaldehyde (1.2 mol), stirred for 30 min and 63 g of formic acid (1.2 mol, 88%) was added dropwise at a temperature of 100 to 110 °C and reacted at about 100 °C for 1 h. Distill out 30 g under reduced pressure (vacuum - 0.094 MPa, kettle temperature 80°C). The distillation ended with 90.0% product and 9.8% impurity (S-2) content. _: The liquid from step 2) was transferred to a 500 ml distillation flask and distilled under reduced pressure at a vacuum of -0.094 mpa. 62°C component was n-butanol ester exchanged down to formic acid as butanol, 121° C DMAEE component that is the product. Collected 121 ° C component 128.3g, yield 96.5%, the Uses. DMAEE is a low odor reactive foaming catalyst, mainly used in rigid packaging foam, also used in molded flexible foam and polyether urethane flexible foam.DMAEE is also an important intermediate, used in polyurethane coatings, surfactants, mine reinforcement and many other fields. Zhongke's organic amine catalyst and curing agent series products will be put into production one after another, and the core catalyst and curing agent products will be used as the basis for the subsequent development of new materials for high value-added polyurethane and epoxy resin by precisely matching the market changes. Integrated manufacturing method of dmae and dmaee in microtubular reactor. A method of integrated preparation of DMAE and DMAEE in microtube reactor is disclosed, which includes the following steps in turn: pumping ethylene oxide and aqueous dimethylamine solution formed by mixing dimethylamine with water as catalyst as materials into the microtube reactor respectively, controlling the molar ratio of ethylene oxide to dimethylamine as 1~2:1; setting the reaction temperature in the microtube reactor as 60~90°C and pressure as 1.3 ±0.2 Pa, and the residence time of the material in the microtubular reactor is controlled to be 15～90s; the effluent from the microtubular reactor is an aqueous solution of DMAE and DMAEE. The method of the present invention has the advantages of high atomic economy, good reaction selectivity, mild reaction conditions, short reaction time, simple catalyst, and simple product separation. Safety information : Risk terminology R21:Harmful in contact with skin. R41:Risk of serious damage to the eyes. Safety Terminology S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. Storage and transportation. Should be kept sealed and stored in a dry, cool, ventilated warehouse Packaging. 200KG/drum Storage: It is recommended to store in a dry and cool area with proper ventilation. After the original packaging, please fasten the lid as soon as possible to prevent the mixing of other substances such as moisture to affect the performance of the product. Do not inhale dust and avoid skin and mucous membrane contact. Smoking, eating and drinking are prohibited in the workplace. After work, shower and change clothes. Store contaminated clothes separately and wash them before use. Maintain good hygiene habits. More:https://www.newtopchem.com/archives/40565